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Baking soda is a basic compound called sodium bicarbonate. Vinegar is a diluted solution that contains acetic acid. The baking soda and vinegar reaction is actually two separate reactions. ... The carbonic acid formed as a result of the first reaction immediately begins to decompose into water and carbon dioxide gas.

The reaction between baking soda (sodium bicarbonate) and vinegar (dilute acetic acid) generates carbon dioxide gas, which is used in chemical volcanoes and other projects.

-Yamauchi Wang

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